三元插层材料的合成及其在聚丙烯老化中的应用          下载免费PDF全文

郭凡  刘志启  王庭胜  李丽娟  李娜 《盐湖研究》2020,28(3)

以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料，以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH)，通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌，探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中，制备MgNiFe-LDH/PP复合材料，通过对材料的加速老化测其力学性能，研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明，当Mg2+:Ni2+:Fe3+=2:1:1，反应温度为140℃、陈化时间为24 h时，合成的MgNiFe-LDH为片状，形貌较为规整，颗粒粒径约为2μm；经加速老化后，填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP，当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变，可明显提高PP的抗老化性能。  相似文献   

城镇化与生态环境耦合的动态模拟——研究进展与展望     

崔学刚  方创琳  刘海猛  刘晓菲  李咏红 《地理学报(英文版)》2020,30(2):333-352

Urbanization and eco-environment coupling is a research hotspot.Dynamic simulation of urbanization and eco-environment coupling needs to be improved because the processes of coupling are complex and statistical methods are limited.Systems science and cross-scale coupling allow us to define the coupled urbanization and eco-environment system as an open complex giant system with multiple feedback loops.We review the current state of dynamic simulation of urbanization and eco-environment coupling and find that:(1)The use of dynamic simulation is an increasing trend,the relevant theory is being developed,and modeling processes are being improved;(2)Dynamic simulation technology has become diversified,refined,intelligent and integrated;(3)Simulation is mainly performed for three aspects of the coupling,multiple regions and multiple elements,local coupling and telecoupling,and regional synergy.However,we also found some shortcomings:(1)Basic theories are inadequately developed and insufficiently integrated;(2)The methods of unifying systems and sharing data are behind the times;(3)Coupling relations and the dynamic characteristics of the main driving elements are not fully understood or completely identified.Additionally,simulation of telecoupling does not quantify parameters and is not systemically unified,and therefore cannot be used to represent spatial synergy.In the future,we must promote communication between research networks,technology integration and data sharing to identify the processes governing change in coupled relations and in the main driving elements in urban agglomerations.Finally,we must build decision support systems to plan and ensure regional sustainable urbanization.  相似文献   

Active capture and anomalous adsorption: New mechanisms for the incorporation of heavy noble gases     

C. M. HOHENBERG  N. THONNARD  A. MESHIK 《Meteoritics & planetary science》2002,37(2):257-267

Abstract— Active capture is a new process for the incorporation of large quantities of heavy noble gases into growing surfaces. Adsorption in the conventional sense involves surface bonding by polarization (Van der Waals forces). What is referred to as “anomalous adsorption” of heavy noble gases involves chemical bonds and can occur when other (more chemically active) species are not available to preempt sites with unfilled bonds. Anomalous adsorption has been observed under conditions of fracture, vacuum deposition and ionizing radiation. Active capture depends upon anomalous adsorption to retain noble gases on a surface long enough to be captured in a growing surface film as it is deposited. The fundamental principle may be the impingement onto the growing film with sufficient energy to liberate surface electrons (work function energy of a few electronvolts) so that they are retained by anomalous adsorption long enough to be entrapped in the growing surface. Trapping efficiencies of ?1% have been observed for Kr and Xe in laboratory experiments, implying a fundamentally new mechanism for the incorporation of heavy noble gases onto surfaces. It may play a role in explaining the large concentrations of planetary noble gases contained in phase‐Q.  相似文献   

Determination of the regional deformation rates of Shanghai and Kashima VLBI stations based on ITRF97     

Zhi-gen Yang  Wen-yao Zhu  C. K. Shum  Feng-chun Shu   《Chinese Astronomy and Astrophysics》2002,26(4):303-502

The vertical deformation rates (VDRs) and horizontal deformation rates (HDRs) of Shanghai VLBI station in China and Kashima and Kashima34 VLBI stations in Japan were re-analysed using the baseline length change rates from Shanghai to 13 global VLBI stations, and from Kashima to 27 stations and from Kashima34 to 12 stations, based on the NASA VLBI global solution glb1123 (Ma, 1999). The velocity vectors of the global VLBI stations were referred to the ITRF97 reference frame, and the Eulerian vectors of different models of plate motion were used for comparative solutions. The VDR of Shanghai station is estimated to be −1.91±0.56 mm/yr, and those of Kashima and Kashima34 stations, −3.72±0.74mm/yr and −8.81±0.84mm/yr, respectively. The difference between the last two was verified by further analysis. Similar estimates were also made for the Kokee, Kauai and MK_VLBA VLBI stations in mid-Pacific.  相似文献   

The mass ratio of Charon to Pluto from Hubble Space Telescope astrometry with the fine guidance sensors     

C.B Olkin  L.H Wasserman  O.G Franz 《Icarus》2003,164(1):254-259

The mass ratio of Charon to Pluto is a basic parameter describing the binary system and is necessary for determining the individual masses and densities of these two bodies. Previous measurements of the mass ratio have been made, but the solutions differ significantly (Null et al., 1993; Young et al., 1994; Null and Owen, 1996; Foust et al., 1997; Tholen and Buie, 1997). We present the first observations of Pluto and Charon with a well-calibrated astrometric instrument—the fine guidance sensors on the Hubble Space Telescope. We observed the motion of Pluto and Charon about the system barycenter over 4.4 days (69% of an orbital period) and determined the mass ratio to be 0.122±0.008 which implies a density of 1.8 to 2.1 g cm⁻³ for Pluto and 1.6 to 1.8 g cm⁻³ for Charon. The resulting rock-mass fractions for Pluto and Charon are higher than expected for bodies formed in the outer solar nebula, possibly indicating significant postaccretion loss of volatiles.  相似文献   

The emission distribution in RR Pictoris     

L. Schmidtobreick  C. Tappert  I. Saviane 《Monthly notices of the Royal Astronomical Society》2003,342(1):145-150

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Spectroscopic studies of three novae     

V. P. Arkhipova  M. A. Burlak  V. F. Esipov 《Astronomy Letters》2002,28(2):100-114

We present our spectroscopic observations of the novae V1425, V1493, and V1494 Aql carried out with the 125-cm telescope at the Crimean Station of the Sternberg Astronomical Institute in the wavelength range 4000–11000 Å. We measured the emission-line intensities, determined the nova shell expansion velocities from the line profile FWHMs and components, and estimated the interstellar reddening from the first members of the Balmer series. The chemical composition of the nova shells is analyzed. Nitrogen and oxygen were found to be overabundant in V1425 and V1494 Aql; the helium abundance turned out to be normal in the two stars.  相似文献   

Pulsar magnetic field for an infinitely conductive accretion disk     

N. R. Sibgatullin  T. A. Doroshenko 《Astronomy Letters》2002,28(11):769-772

The magnetic-field distribution outside a flat, infinitely conductive unbounded disk in the field of a point magnetic dipole is determined. A relationship is established between the problem of magnetic-field determination and the problem of the flow of an ideal incompressible fluid around an infinitely thin disk.  相似文献   

Cosmological constraints from the local X-ray luminosity function of the most X-ray-luminous galaxy clusters     

S. W. Allen  R. W. Schmidt  A. C. Fabian  H. Ebeling 《Monthly notices of the Royal Astronomical Society》2003,342(1):287-298

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EFFECTS OF FISH OIL,DHA OIL AND LECITIHIN IN MICROPARTICULATE DIETS ON STRESS TOLERANCE OF LARVAL GILTHEAD SEABREAM（SPARUS AURATA）     

刘镜恪王文琪  李岿然雷霁霖 《中国海洋湖沼学报》2002,20(4):338-343

The effects of natural fish oil,DHA oil and soybean lecithin in microparticulate diets on stress tolerance of larval gilthead seabream(Sparus aurata)were investigated after 15 days feeding trials.The tolerance of larval gilthead seabream to various stress factors such as exposure to air(lack of dissolved oxygen),changes in water temperature(low)and salinity(high) were determined.This study showed that microparticulate diet with natural fish oil and soybean lecithin was the most effective for in-creasing the tolerance of larval gilthead seabream to various stresses,and that microparticulate diet with natural fish oil and palmitic acid(16:0)was more effective than microparticulate diet with DHA oil and soybean lecithin.  相似文献